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null (Ed.)The ability of a phosphine-appended-2,2′-bipyridine ligand ((Ph 2 P) 2 bpy) to serve as a platform for late-stage ligand modifications was evaluated using tetrahedral (Ph 2 P) 2 bpyFeCl 2 . We employed a post-metalation Staudinger reaction to install a series of functionalized arenes, including those containing Brønsted and Lewis acidic groups. This reaction sequence represents a versatile strategy to both tune the ligand donor properties as well as directly incorporate appended functionality.more » « less
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Taher, Deeb; Nawara-Hultzsch, Agnieszka J.; Bhuvanesh, Nattamai; Hampel, Frank; Gladysz, John A. (, Journal of Organometallic Chemistry)
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Kharel, Sugam; Joshi, Hemant; Bierschenk, Stephen; Stollenz, Michael; Taher, Deeb; Bhuvanesh, Nattamai; Gladysz, John A. (, Journal of the American Chemical Society)
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